Abstract
The statistical mechanics of a polydisperse system of charged particles with sticky interactions is studied in the mean spherical/Percus–Yevick approximation. The excess thermodynamic properties are calculated, taking as a reference system the sticky hard spheres mixture and are given in terms of a single scaling parameter ΓT. When the sticking probability is of the form λij=λiλj, then all the equations are explicitly solvable for arbitrary mixtures of charged systems. We obtain explicit expressions for the thermodynamic properties, structure function, and the Laplace transform of the pair distribution function.
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