Abstract

HighlightsThe engineering design principles for enhancing interfacial contact between the electrodes (Li anodes and S cathode) and solid-state electrolytes in solid-state Li–S batteries are classified and discussed.Research progresses of experimental strategies for reducing interfacial impedance in solid-state Li–S batteries are summarized.Challenges and future perspectives of rational interfacial strategies in solid-state Li–S batteries are highlighted.

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