A review of desalting process techniques and economic analysis of the recovery of salts from retentates

Electrodialysis desalination: New units

Novel Tri Hybrid Desalination Plants

Water scarcity is an alarming global problem for a growing population with depleting sources of fresh water. Desalination is thus becoming an important solution for water management to address such looming shortage of the municipal water supply. At present, several technologies dominate the desalination industry which can be categorized either as a thermal process such as multi-stage flash distillation or a membrane process such as that of reverse osmosis. New desalination systems are also being developed to make the process more cost-effective and energy efficient. Hence, this work proposes a systematic approach for optimal selection of desalination systems using fuzzy analytic hierarchy process (FAHP) and grey relational analysis (GRA). Fuzzy AHP addresses the vagueness involve in the trade-off of the criteria or attributes used in evaluating the alternatives. On the other hand, the GRA solves the multiple criteria decision problem by aggregating the entire range of performance attribute values for every alternative into a single score in spite of incomplete information. An illustrative case study was presented wherein five desalination systems namely reverse osmosis (RO), combined reverse osmosis and forward osmosis (RO-FO), electrodialysis (ED), multi-stage flash distillation (MSF), and combined forward osmosis and membrane distillation (FO-MD) were evaluated. These desalination systems were compared to each other with respect to energy requirement, land footprint, system efficiency, economic viability, and maturity of technology. Sensitivity analysis was also done to determine the robustness of the modeling results from the variation of weights of the criteria.

Performance evaluation of two RO membrane configurations in a MSF/RO hybrid system

On the brine re-utilization of a multi-stage flashing (MSF) desalination plant

Hybrid systems in seawater desalination-practical design aspects, status and development perspectives

Desalination is probably the only means for fresh water supply to countries in decertified climate. The majority of GCC counties rely on desalinated water for fresh water supply to major cities. Over 70% of the desalinated water in the GCC comes from thermal desalination plants including Multi Stage Flash (MSF) and Multi Effect Distillation (MED). The new trend in the desalination plant in the GCC is 30% Reverse Osmosis (RO) and 70% thermal. However, these percentages vary from one to another country depending on feed water quality and expertise. For example, Oman Sea has lower salinity than the Gulf water and hence Oman uses more RO for desalination than MED and MSF. This decision is also driven by economy as RO process less energy intensive and hence the produced water is less expensive as compared to thermal plants. On the contrary, Qatar and Kuwait use more MSF followed by MED due to the high salinity and low quality feed water. This is also because trials of RO in both Qatar and Kuwait were not successful because of the problems of membrane fouling and restrict pre-treatment requirements due to the quality of the water intake.The advantages of RO over thermal technologies are well known in terms of lower energy consumption and the cost of produced water; but are not yet taken advantage of in the GCC zone. One of the reasons is blamed on high feed water salinity and bad water quality; other reasons such as lack of experience, red tides and reliability are contributed to the dominance of thermal plants. However, field experience showed that good pretreatment and optimized RO design may overcome the problems of high feed salinity and bad water quality. Several RO plants, such as Fujairah in UAE, are good examples of a working RO technology in the harsh water environment. Good RO design includes design and optimization of both pretreatment and post-treatment. Field experience showed that most of RO plants failure was due to inefficient pretreatment which resulted in providing low quality water to the RO membrane that caused fouling. Fouling, including biological and scaling, can be handled once an efficient pretreatment process is available. Recent advances in pre-treatment techniques include the combination of Forward Osmosis (FO) with RO among other methods. Recent studies by the authors including commercial implantations have shown that the combination of FO with RO addresses the most technical challenge of RO process and that is fouling, which results in lower energy consumption and less chemical additives. Experience showed fouling in FO process in reversible, i.e. can be removed by backlashing while fouling in conventional RO process is irreversible.In this study, the feasibility of integrating FO with RO process for the desalting of the Gulf water in Qatar is presented. The results are expressed in terms of specific energy consumption, process recovery, produced water quality, chemical additives and overall process cost.The implementation of RO for desalination is not only reducing the cost of desalination but also the environmental impact. More R&D should be done to provide useful data about RO application and suitability for the Gulf water. The R&D should be focused on laboratory to market development of RO technology using rigorous lab scale and pilot plant testing program.

Despite being a mature process, production of fresh water using desalination is still a challenge. Desalination is broadly divided into two categories; thermal desalination processes, such as multi-stage flash, and semi-permeable membrane process, such as Reverse Osmosis (RO). This work is aimed at developing correlations for water permeability coefficient (Kw) and salt permeability coefficient (Ks) as a function of feed salinity and pressure using experimental data for a continuous RO process. For three different feed salinities of 15, 25, and 35 g/L at two different pressures of 40 and 45 bara experimental values of Ksand kwvalues are taken from the literature. Planar and ellipsoidal least square methods are used to correlate kwand Ksas a function of feed salinity and pressure, which are then embedded within the continuous RO process model to evaluate the process performance in terms of maximising the recovery ratio while optimizing the area and pressure to get the desired freshwater salinity. gPROMS model builder is used to simulate and optimise the process.

Coupling of a nuclear reactor to hybrid RO-MSF desalination plants

Hybrid Desalination Systems: Alternative Designs of Thermal and Membrane Processes.

A comparative study of RO and MSF desalination plants

A comparative study of RO and MSF desalination plants

Systematic Analysis Reveals Thermal Separations Are Not Necessarily Most Energy Intensive

Integrating hybrid systems with existing thermal desalinationplants

Agricultural drainage water (ADW) represents a potential source for fresh water after receiving appropriate treatments to satisfy the water quality requirements. Desalination of ADW with medium salinity and moderate contamination with organic and inorganic chemical pollutants could provide a techno-economically feasible approach for facing water scarcity in arid areas. The current work presents a conceptual zero liquid discharge ADW desalination system proposed to treat 300,000 m3/d. The system is based on pretreatment to remove impurities harmful to desalination by staged reverse osmosis (RO) membrane. The brine from the last RO stage is treated via thermal vapor compression followed by evaporation in solar ponds to recover more fresh water and salts of economic value. The essential technical features of the proposed system components are formulated. The proposed system components and its technical and economic indicators are deduced using available software for water pretreatment, RO membrane, desalination, thermal desalination, and solar evaporation ponds. The system provides total distilled water recovery of about 98% viz. 294,000 m3/d in addition to recovered salts of 245,000 t/y. The net cost of water production amounts to USD 0.46 /m3. The environmental considerations of the system are addressed and advantages of applying zero liquid discharge system are elucidated.