Abstract
A novel heteroditopic porphyrin-based ion pair receptor with four ureas and four triazoles on the same side of the porphyrin ring was synthesized through click chemistry. This receptor showed high affinity to complex with the ion pairs KCl, NaCl and NH4Cl in 1:1 binding stoichiometries with association constants of 2.48 (± 0.43) × 104, 1.06 (± 0.02) × 105, and 1.97 (± 0.04) × 105 M[Formula: see text], respectively. After complexation with the ion pairs, fluorescence quenching of the porphyrin was observed, which enables its potential applications in ion detection.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Disclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.