Abstract
Reactive reagents can be prepared by means of olefin cross-metathesis. A wide variety of functionalized allyl boronates were synthesized and were found to react cleanly with aldehydes to afford homoallylic alcohols, without prior purification (see scheme). Olefins that bear allylic ethers, halides, protected aldehydes, and sterically encumbering groups are viable substrates for this reaction.
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