Abstract

Novel Na3Li3Sc2F12 microcrystals with cubic-phase structure, (110)-truncated cubooctahedral morphologies, as well as self-activated white-light luminescence are reported for the first time. Doping of this cubic polymorph with optically active lanthanide ions or ion-pairs illustrates its suitability as a host lattice for the UC/DC luminescence, which opens a window of additional hosts for further fundamental research and various applications.

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