Abstract
A one-pot CAN-mediated oxidative alkylation–nitration of endo-dicyclopentadiene and norbornene with 1,3-dicarbonyl compounds is described. The key step involves the Wagner–Meerwein rearrangement of 2 which leads to the exo-dicyclopentadienyl nitrate 4.
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More From: Journal of the Chemical Society, Perkin Transactions 1
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