Abstract
The study focuses on fabricating and utilizing a lignin-steel sludge magnetic carbon composite (SLNa) to efficiently remove two dyes from an aqueous medium. The SLNa composite was fabricated through a simple two-step strategy involving the activation and thermal treatment of lignin and steel sludge. The SLNa possessed lignin and steel sludge starring properties, viz. abundant surface functionalities, graphitic carbon matrix, and magnetic characteristics. The synergistic combination of lignin and steel sludge resulted in composite's high adsorption potential for Methylene Blue (MB; 153.92 mg/g) and Acid Orange 7 (AO7; 64.84 mg/g) in batch mode. Additionally, the rapid adsorption kinetics and effective dye removal for MB (> 99 %) and AO7 (72 %) from simulated effluent revealed the potential of fabricated adsorbent for water remediation. Furthermore, the composite's applicability for continuous adsorption was also evaluated through a series of dynamic flow experiments using fixed-bed column systems. The demonstrated efficacy of SLNa, viz., 48.18 and 15.00 mg/g for MB and AO7, respectively, at high adsorbent loading and lower dye concentrations, highlights its potential for scalable water treatment applications. Thus, the versatility and effectiveness of the novel composite underscore its potential for practical application in both batch and continuous water remediation processes.
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