Abstract
The dicarboxylic flexible ligand 4-((2-carboxyethyl)amino)benzoic acid (LH3) has been synthesized and its reaction with Pb(NO3)2 lead to the formation of a 3D coordination polymer formulated as {[Pb(LH)(H2O)]⋅H2O}n (1) which presents a very interesting structure with an sra underlying topology. Thermal stability studies combined with X-ray powder diffraction suggest that the molecular material displays soft crystalline properties; upon heating it loses its water content changing its structure, while upon rehydration under a variety of conditions the original structure is obtained.
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