Abstract
AbstractAn exact spectrophotometric method has been devised for the evaluation of stability constants of metal complexes.This method is developed for complex‐formation in two steps and is especially useful when complex‐formation occurs in acid solutions where the conventional Calvin‐Bjerrum titration method becomes inaccurate. Knowledge of the extinction coefficients of the different species in the solution is necessary.The method has been successfully applied to the determination of stability constants of the complexes of 8‐hydroxyquinoline and 8‐hydroxyquinoline‐5‐sulphonic acid with copper in ethanol/water mixtures.The conditions are examined which must be satisfied in order to obtain accurate results by this method [equations (11) and (15)].
Sign-in/Register to access full text options 
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
