Abstract
Chromous ion reacts with 3-pyridineacrylic acid, 4-pyridineacrylic acid, maleic acid and fumaric acid to give remarkably inert organochromium(III) species. These species were isolated by ion exchange from acidic aqueous media and were characterized by a variety of techniques. An organochromium(III) compound was even isolated from the Cr(III)-3-pyridineacrylic acid aqueous mixture in solid form. In all the organometallic compounds reported in this paper chromium(III) is believed to be σ-bonded to carbonyl by the general scheme ▪.
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