A New Plasticating Model for Amorphous and Semi-crystalline Polymers in Single Screw Extruders

Abstract

Abstract Polymeric thermoplastic materials can be subdivided in amorphous and semi-crystalline ones. In contrast to semi-crystalline polymers amorphous thermoplastic materials have no defined phase transition and hence no melt enthalpy. The glass transition region describes the change of the material behaviour from the state of a rubber like to an under-cooled fluid (glassy state). Setting the melt enthalpy in the Stefan-Neumann problem zero gives no valid results for the solid bed profile. Thus this condition is unsuitable for describing the plasticating process of amorphous polymers. In this paper a new model for the plastication of amorphous and semi-crystalline polymers in single screw extruders is presented. Therefore a new calculation method for the determination of the moving velocity between the glassy solid bed and the softened film region on the barrel surface is developed. The whole enthalpy to heat up the polymer on a critical flow temperature in the screw channel is considered.