Abstract
Ethanolic tetracarbonylhydridoferrate combined with aqueous succinaldehyde is very efficient for the selective transformation of an amino group into a pyrrolidine ring. A large variety of both aliphatic and aromatic amines react with aqueous succinaldehyde in the presence of tetracarbonyl-hydridoferrate at room temperature under carbon monoxide to give the corresponding N-alkyl-and N-arylpyrrolidines in good to excellent yields.
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