Abstract
A two-dimensional (2D) water-stable Cd (II) luminescent coordination polymer (1), namely {[CdLCl2]}n, was obtained through assembly of a new 2-deoxy-d-ribose derivative ligand (L) with CdCl2, 1 showed high stability in water. Further investigation showed that 1 can be used as luminescent probe for the organoarsenic compound Roxarsine (ROX) with high selectivity and sensitivity, high quenching constants (KSV = 2.34 × 104 M−1), low limits of detection (LOD) (0.16 μM) and good recyclability in aqueous media. In addition, this luminescent probe can detect some inorganic harmful ions (Fe3+, Cr2O72− and CrO42−) with excellent versatility. The detection mechanism was proved that the quenching was caused by competitive absorption and resonance energy transfer effect between 1 and analytes. More strikingly, a simple 1-based test strip was developed owing to the quick response and recyclability of 1, which shows visible quenching signals under UV light even when analytes concentrations are as low as 5 μM. This work has provided an effective method for the design of multifunctional CP luminescent sensors for pollutants detections in aqueous media.
Sign-in/Register to access full text options 
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
