A large barocaloric effect and its reversible behavior with an enhanced relative volume change for Ni42.3Co7.9Mn38.8Sn11 Heusler alloy

Abstract

Both the barocaloric effect (BCE) and its reversible behavior during martensitic transformation (MT) have been experimentally investigated in Ni42.3Co7.9Mn38.8Sn11 quaternary Heusler alloy. The experimental results show that the studied alloy experiences the MT from the ferromagnetic L21-type cubic structure to the paramagnetic-like three-layered (3M) modulated monoclinic structure, resulting in a value of ∼1.1% for the relative volume change ε between two phases. Due to appearance of an enhanced ε, the migration rate of martensitic transformation with respect to the hydrostatic pressure reaches ∼4.7 K/kbar, while a high transition entropy change (∼28 J/kg K) is still maintained. Based on an indirectly estimated method, the calculated maximum value for isothermal entropy change ΔST achieves ∼ -23 J/kg K with the pressure change of 6.2 kbar, which yields the values of ∼10 K for adiabatic temperature change ΔTad and ∼786 J/kg for relative cooling power (RCP), performing a large BCE. According to the change of phase fraction at selected hydrostatic pressures, a detailed schematic diagram has been established to evaluate the reversibility of this effect. With applying an external cyclic pressure of 6.2 kbar, the maximum repeatable values calculated for both ΔST and ΔTad are decreased to ∼ -15 J/kg K and ∼5 K, respectively. This is attributed to an insufficient driving force, which can only partially transform this material, leading to a reversible MT appeared in the mixed state.