Abstract

A study of photochemical reactions of uranyl ions in aqueous acid solutions was carried out by means of flash photolysis. Short-lived absorption (∼ 10 −4 s) was observed on flash excitation of uranyl ion in solution and was assigned to singlet-singlet transitions. In the presence of certain organic substances a new transient absorption was detected due to production of U v intermediate. Deactivation pathways of excited ion (UO 2+ 2) * and decay kinetics of U v were studied. Values of rate constants for some elementary processes were determined.

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