Daridon, J.L., Lagourette, B., Saint-Guirons, H. and Xans, P., 1993. A cubic equation of state model for phase equilibrium calculation of alkane + carbon dioxide + water using a group contribution kij. Fluid Phase Equilibria, 91: 31-54. This paper presents a general procedure for the calculation of phase equilibria of paraffin, CO2, water and mixtures thereof based on a modified Peng and Robinson equation of state linked with a group contribution kij. This procedure gives a good representation of the transitions of pure substances, including water and heavy alkanes (C10 to C20) as well as carbon dioxide-alkane mixtures. It also provides quite satisfactory results for calculation of mutual solubilities of water and alkanes (or carbon dioxide) in conditions of pressure between 0.1 and 50 MPa and temperature between 293 and 523 K.

Full Text

Published Version
Open DOI Link

Get access to 115M+ research papers

Discover from 40M+ Open access, 2M+ Pre-prints, 9.5M Topics and 32K+ Journals.

Sign Up Now! It's FREE

Talk to us

Join us for a 30 min session where you can share your feedback and ask us any queries you have

Schedule a call