Abstract
A 2-periodic copper–organic framework of 1 has been deliberately obtained via solvothermal reaction between Cu(NO3)2·3H2O and a V-shaped highly conjugated organic linker. Single-crystal X-ray structural analyses reveal that 1 displays a 3D stacking structure along with channel-typed interior architectures decorated with amino and trifluoromethoxy functionalized groups. 1 demonstrates not only notably selective encapsulation of small-sized MB and MO molecules with high adsorption rate, but also efficient photodegradation activities through decomposing MB, MO and large-sized phthalocyanine of reactive blue 21 under visible light irradiation.
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