Abstract
An efficient regio- and stereoselective method for the synthesis of cyclic trithiocarbonates on carbohydrate skeleton is described. A freshly prepared solution of sodium trithiocarbonate reacts with cis-oriented epoxytriflate pentoses 7– 11 to yield the corresponding cyclic trithiocarbonates 12– 16 . Structures of all new compounds are established through MS, 1H and 13C NMR techniques.
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