A comparative analysis of the mechanical behavior of carbon dioxide and methane hydrate-bearing sediments

The injection of carbon dioxide into methane hydrate-bearing sediments causes the release of methane and the formation of carbon dioxide hydrate. This phenomenon known as CH4-CO2 replacement creates a unique opportunity to recover an energy resource, methane, while entrapping a greenhouse gas, carbon dioxide. The paper “A comparative analysis of the mechanical behavior of carbon dioxide and methane hydrate-bearing sediments” by Hyodo et al. (2014) investigates stress-strain curves, shear strengths, and the effects of hydrate saturation, effective stress, and temperature on the mechanical behaviors of hydrate-bearing sediments that allow us to assessing the feasibility of CH4-CO2 replacement method.

As a clean energy source, natural gas hydrate resources are essential to the development of energy in the twenty-first century. However, the degree of consolidation of the hydrate reservoir is low, and complex accidents such as wellbore instability, reservoir collapse, and gas production leakage will be caused if improperly exploited. The laboratory employs a self-developed triaxial shear test equipment that operates under high pressure and low temperature conditions. This equipment is specifically designed to determine the mechanical parameters and strength characteristics of methane hydrate bearing sediment (MHBS) samples. It is used to create water-saturated hydrate deposits with varying levels of saturation. The synthesis of MHBS samples with varying saturations is achieved by precisely regulating the amount of water. The saturation of MHBS is then determined and confirmed by the utilization of the “water content method” and the “gas collection method.” Triaxial shear tests are conducted on MHBS to examine the impact of hydrate saturation on the mechanical parameters and strength behaviours of MHBS. The experimental findings demonstrate that the presence of hydrate crystals enhances the robustness of the depositing medium. The stress-strain curves of MHBS have a hyperbolic shape, indicating strain hardening features. The stress-strain curves may be categorized into three distinct stages: the initial elastic deformation, followed by a slow shift to the initial yield deformation, and ultimately leading to strain hardening. As axial strain rises, the behaviour of the MHBS transitions progressively from elastic deformation to plastic deformation. The shear strength and initial yield strength of MHBS enhance with higher hydrate saturation. The reason for this is that as the hydrate saturation rises, the influence of hydrate crystals on the enhancement of sediment strength becomes more pronounced. However, the initial yield strain of each MHBS sample is between 0.5% and 1.5%, and the difference is not significant. When the hydrate saturation rises gradually, the cohesion of MHBS enhances. Nevertheless, the hydrate saturation has a very minor impact on the internal friction angle.

A discrete element simulation considering liquid bridge force to investigate the mechanical behaviors of methane hydrate-bearing clayey silt sediments

Mechanical properties of methane hydrate-bearing sandy sediments under various temperatures and pore pressures

The geomechanical behavior of methane hydrate bearing sediments (MHBS) is influenced by many factors, including temperature, fluid pressure, hydrate saturation, stress level, and strain rate. The paper presents a visco-elastoplastic constitutive model for MHBS based on an elastoplastic model that incorporates the effect of hydrate saturation, stress history, and hydrate morphology on hydrate sediment response. The upgraded model is able to account for additional critical features of MHBS behavior, such as, high-dilatancy, temperature, and rate effects. The main components and the mathematical formulation of the new constitutive model are described in detail. The upgraded model is validated using published triaxial tests involving MHBS. The model agrees overly well with the experimental observations and is able to capture the main features associated with the behavior of MHBS.

It is important to determine the volumetric change properties of hydrate reservoirs in the process of exploitation. The Skempton pore pressure coefficient A can characterize the process of volume change of hydrate-bearing sediments under undrained conditions during shearing. However, the interrelationship between A value responses and deformation behaviors remain elusive. In this study, effects of hydrate saturation and effective confining pressure on the characteristics of pore pressure coefficient A are explored systematically based on published triaxial undrained compression test data of hydrate-bearing sand and clay-silt sediments. Results show that there is a higher value of the coefficient A with increasing hydrate saturation at small strain stage during shearing. This effect becomes more obvious when the effective confining pressure increases for hydrate-bearing sand sediments rather than hydrate-bearing clayey-silt sediments. An increasing hydrate saturation leads to a reduction in A values at failure. Although A values at failure of sand sediments increase with increasing effective confining pressure, there are no same monotonic effects on clayey-silt specimens. A values of hydrate-bearing sand sediments firstly go beyond 1/3 and then become lower than 1/3 at failure even lower than 0, while that of hydrate-bearing clayey-silt sediments is always larger than 1/3 when the effective confining pressure is high (e.g., >1 MPa). However, when the effective confining pressure is small (e.g., 100 kPa), that behaves similar to hydrate-bearing sand sediments but always bigger than 0. How the A value changes with hydrate saturation and effective confining pressure is inherently controlled by the alternation of effective mean stress.

Triaxial tests on the overconsolidated methane hydrate-bearing clayey-silty sediments

Geomechanical behavior of methane hydrate-bearing sediment (MHBS) plays a major role in evaluation of the stability of a hydrate reservoir. A series of triaxial compression tests were conducted on MHBS to study the influence of temperature and pore pressure conditions on its mechanical behaviors. The experimental results show that temperature and pore pressure have a significant effect on the stress–strain curve, stiffness, and strength of MHBS. As temperature decreases and/or pore pressure increases, the stress–strain curve manifests an enhanced strain-softening characteristic, stiffness, and strength. Furthermore, MHBS cohesion also tends to exhibit a significant increase, but its internal friction angle almost remains constant with decreasing temperature and/or increasing pore pressure. These findings imply that the change in temperature and pore pressure affects the strength of MHBS, which occurs predominately due to change in its cohesiveness. To describe these impacts, a phase state parameter is introduced to characterize the temperature and pore pressure conditions. Meanwhile, three empirical formulas for relating the secant modulus, strength and cohesiveness to phase state parameter are presented. Good agreement between simulation and measured data indicates that the phase state parameter can effectively describe temperature and pore pressure conditions. The proposed empirical formulas are able to address the influences of temperature and pore pressure conditions on geomechanical characteristics of MHBS.

Effect of wellbore design on the production behaviour of methane hydrate-bearing sediments induced by depressurization

Mechanical behaviors of permafrost-associated methane hydrate-bearing sediments under different mining methods

Mechanical behavior of clayey methane hydrate-bearing sediment: Effects of pore size and physicochemical characteristics using a novel DEM contact model

The deep subseafloor biosphere is among the least-understood habitats on Earth, even though the huge microbial biomass therein plays an important role for potential long-term controls on global biogeochemical cycles. We report here the vertical and geographical distribution of microbes and their phylogenetic diversities in deeply buried marine sediments of the Pacific Ocean Margins. During the Ocean Drilling Program Legs 201 and 204, we obtained sediment cores from the Peru and Cascadia Margins that varied with respect to the presence of dissolved methane and methane hydrate. To examine differences in prokaryotic distribution patterns in sediments with or without methane hydrates, we studied >2,800 clones possessing partial sequences (400-500 bp) of the 16S rRNA gene and 348 representative clone sequences (approximately 1 kbp) from the two geographically separated subseafloor environments. Archaea of the uncultivated Deep-Sea Archaeal Group were consistently the dominant phylotype in sediments associated with methane hydrate. Sediment cores lacking methane hydrates displayed few or no Deep-Sea Archaeal Group phylotypes. Bacterial communities in the methane hydrate-bearing sediments were dominated by members of the JS1 group, Planctomycetes, and Chloroflexi. Results from cluster and principal component analyses, which include previously reported data from the West and East Pacific Margins, suggest that, for these locations in the Pacific Ocean, prokaryotic communities from methane hydrate-bearing sediment cores are distinct from those in hydrate-free cores. The recognition of which microbial groups prevail under distinctive subseafloor environments is a significant step toward determining the role these communities play in Earth's essential biogeochemical processes.

The structure of natural hydrate-bearing sediments that exist offshore or onshore is a combination of coarse-grained sediments and fine-grained particles. During gas production from hydrate-bearing sediments, fine particles may migrate with the flowing fluids within pore space and cause clogging of the pore space of the porous media. Therefore, fine particles play a significant role during methane production from hydrate-bearing sediments as it impact the overall sediment formation performance and production efficiency. The migration of fine particles and its impact on clogging have been investigated in a single-phase flow, but it has not been clearly understood in a multi-phase flow. This research focuses on the study of fines migration and clogging behavior during single and multi-phase flow which can be implicated in gas production from hydrates bearing sediments. Microfluidic pore models that mimic porous media with different pore throat sizes were fabricated and utilized to study fines migration and clogging behavior in porous media. Artificial particles and natural fine particles were selected to represent fine particles. The impact of flow rate, pore-fluid types, particle concentration, and pore-throat to fine particle size ratio was investigated. Fine particles used in this research include polystyrene latex particles, silica, and kaolinite. Pore-fluids used in this study include deionized (DI) water, and sodium chloride (NaCl) brine (2M concentration). The particle concentrations covered from 0.1% to 10%. And the pore-throat widths were fabricated from 40 μm to 100 μm. Single-phase flow experiments were conducted to show that the concentration of fine particles required to form clogging in pores increased as flow rate decreased. The results obtained using polystyrene latex particles provide the insight at a relatively higher flow rate (50 μl/min) than literature studies that fine particles with 2% concentration can migrate in the pore throat without bridge or clogging at the various pore throat and fine particle size ratios (o/d = 2.6∼36.4). Furthermore, silica presents higher critical clogging concentration (0.5% in brine) compared with kaolinite (0.2% in brine) when the pore-throat width equal to 60 μm due to the larger pore throat and fine particle size ratio. On the other hand, the findings show that clogging easily occurred at a lower pore-throat to fine particle size ratio even with a few number of fine particles. In addition, pore-fluid type directly influences the tendency of fine's to form clusters which in turn impacts the clogging behavior. For instance, silica fines clogging easier occurs in brine solution compare within deionized water due to larger cluster size in brine, while kaolinite shows an opposite result which means the kaolinite has higher clogging possibility in deionized water compared within brine solution. On the other hand, findings of multi-phase flow experiments show that fine particles accumulate along the liquid-gas interface and migrate together, which in turn cause bridging or clogging to occur easily in pores. These observations imply that a multi-phase flow during gas production could easily form clogging in pores, in which the flow permeability of porous media decreases even though clogging has not occurred in the same conditions with a single-phase flow. Thus, the permeability of porous media in engineering applications should be estimated by considering relatively easy clogging in pores in a multiphase flow compared to a single-phase flow. Findings of this research show the vital impact of pore-fluids and fluid-fluid interphase on fine particles migration and clogging in porous media. It provides a better understanding of the fines migration and clogging mechanisms. In addition, the results indicate the need to understand the types of fines and fluids in reservoir before evaluating if there will be a clogging potential during gas production from hydrates bearing sediments.

Thermal conductivity of methane hydrate-bearing Ulleung Basin marine sediments: Laboratory testing and numerical evaluation

Characterizing spatial distribution of ice and methane hydrates in sediments using cross-hole electrical resistivity tomography