Abstract

The conductivity ( σ) of sulphosalicylic acid and its composites with iron(III) sulphosalicylate (1:4 molar) is measured using impedance spectroscopy and the Hebb–Wagner polarization method. The conductance is found to be purely protonic with typical values of σ(25°C)=4.1×10 −4 and 3.0×10 −4 S cm −1, respectively. The exchange currents at TiH x | H +-solid electrolyte interphase boundaries increase with increasing partial pressure of H 2 in mixtures with argon.

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