Abstract
The 13C NMR spectra of a variety of isonitrile complexes have been studied. The isonitrile carbon shielding trend is consistent with the hypothesis that some π-back bonding occurs in zero oxidation state complexes but is not important in positive oxidation state complexes. A metal triad shielding trend is observed with the isonitrile complexes as has been found previously in carbonyl-, carbene-, and alkylmetal compounds.
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