Abstract

A hitherto unreported long-period stacking-ordered (LPSO) phase, designated 12R, was observed in a Mg80Ni5Y15 (at.%) alloy. Microstructure was investigated by electron diffraction and high-angle annular dark-field scanning transmission electron microscopy. Results show that the 12R has a trigonal lattice (a=b=1.112nm, c=3.126nm, α=β=90°, and γ=120°). Unit cell of the 12R is consisted of three ABCA-type building blocks and each building block contains dominant Ni6Y8-type building clusters. A sound structural model is proposed based on relative positions of Ni6Y8 clusters in neighboring building blocks.

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