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Abstract

Impregnation technique is an attractive alternative for manufacturing highly radiotoxic 233U bearing thoria based mixed oxide fuel pellets, which are remotely treated in hot cell or shielded glove-box facilities. This technique is being investigated to fabricate the fuel for the forthcoming Indian Advanced Heavy Water Reactor (AHWR). In the impregnation process, porous ThO2 pellets are prepared in an unshielded facility which are then impregnated with 1.5 molar uranyl nitrate solution in a shielded facility. The resulting composites are dried and denitrated at 500 °C and then sintered in reducing/oxidizing atmosphere to obtain high density (Th,U)O2 pellets. In this work, the densification behaviour of ThO2–2% UO2 and ThO2–4% UO2 pellets was studied in reducing and oxidizing atmospheres using a high temperature dilatometer. Densification was found to be larger in air than in Ar–8% H2. The characterization of the sintered pellets was made by optical microscopy, scanning electron microscopy (SEM) and electron probe microanalysis (EPMA). The grain structure of ThO2–2% UO2 and ThO2–4% UO2 pellets was uniform. The EPMA data confirmed that the uranium concentration was slightly higher at the periphery of the pellet than that at the centre.