Abstract
Abstract Two novel three-dimensional (3D) coordination polymers [ Cu 3 II ( mtta ) 6 ] n (1) and [ Cu 2 II Cu 3 I ( trz ) 4 Br 3 ] n ·nH2O (2) (mtta = 5-methyltetrazolate, trz = 1,2,4-triazole) were synthesized and structurally characterized. Complex 1 shows a 3D porous metal–organic framework. By the topology analysis, the complicated architecture of 1 can be simplified to be the 4-connected diamond-type net. Compound 2 is a two-fold interpenetrating 3,5-connected 3D framework with new topology.
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