Abstract
The title compound, C16H12O5S, was prepared by oxidation of 2-methyl-5,6-methylenedioxy-3-phenylsulfanyl-1-benzofuran with 3-chloroperoxybenzoic acid. The phenyl ring makes a dihedral angle of 83.64 (4)° with the mean plane of the 5,6-(methylenedioxy)benzofuran fragment. The crystal structure is stabilized by C—H⋯π interactions between a benzene H atom of the 5,6-(methylenedioxy)benzofuran unit and the phenyl ring of the phenylsulfonyl substituent. Additionally, the crystal structure exhibits inter- and intramolecular C—H⋯O interactions.
Highlights
The crystal structure is stabilized by C—H interactions between a benzene H
Cg is the centroid of the C9–C14 benzene ring
Symmetry codes: (i) −x, −y+2, −z+1; (ii) −x+1, −y+1, −z+1; (iii) −x, −y+1, −z+1
Summary
The phenyl ring makes a dihedral angle of 83.64 (4) with the mean plane of the 5,6(methylenedioxy)benzofuran fragment. The crystal structure is stabilized by C—H interactions between a benzene H atom of the 5,6-(methylenedioxy)benzofuran unit and the phenyl ring of the phenylsulfonyl substituent. The crystal structure exhibits inter- and intramolecular C—
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