Abstract
The title compound, C24H19F6NS, is a new hybrid diarylethene derivative with a 3-thienyl and a six-membered aryl unit as the substituents. In the crystal structure, the F atoms of the central hexafluorocyclopentene ring are disordered, with site occupancies of 0.641 (3) and 0.359 (3). The molecule adopts a photoactive antiparallel conformation. The distance between the two reactive C atoms, between which a new C—C bond can be formed upon UV irradiation, is 3.504 (5) A. The dihedral angle between the thienyl ring and the adjacent phenyl ring is 12.4 (2)°. The dihedral angle between the central cyclopentene ring and the thienyl ring is 46.6 (7)°, and that between the central cyclopentene ring and the dimethylaminophenyl ring is 49.7 (4)°.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callMore From: Acta Crystallographica Section E Structure Reports Online
Disclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
