Abstract
The use of 2-pyridyloximate(-1) ligands, (py)C(R)NO − [R = H, Ph, 2-pyridyl (py)] in cobalt and nickel(II) chemistry has been investigated and led to four families of clusters. A representative member of each family, namely [ Co II Co 2 III { ( py ) C ( ph ) NO } 6 ] ( PF 6 ) 2 ( 1), [ Co 2 II Co 2 III ( OH ) 2 ( O 2 CMe ) 2 { ( py ) 2 CNO } 4 ( MeOH ) 2 ] ( ClO 4 ) 2 ( 2), [Ni 9(OH) 4{(py)CHNO} 10(H 2O) 8]{N(CN) 2} 3(ClO 4) [ 3{N(CN) 2} 3(ClO 4)] and [Ni 4(O 2CMe) 4{(py)C(ph)NO} 4(MeOH) 2] ( 4) is briefly structurally and magnetically described.
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