Abstract
The 2-methyl-1,3-indandione and 4-nitrophenyl groups are trans to each other. The five-membered ring of the indandione moiety adopts an envelope comformation. The phenyl and azo groups are not coplanar because of steric hindrance between the lone-pair orbitals at the carbonyl O and β-N atoms [C1'-N=N=112.6(6) and 112.8(6) o for molecules A and B, respectively]
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