Abstract

In the title compound, C29H22Br2O3, the dihedral angles between the mean planes of the benzene rings within each biphenyl group are 26.7 (8) and 30.9 (8)°. The mean planes of the terminal and inner benzene rings of the biphenyl groups bonded through a propan-1-one group in the V-shaped mol­ecule are oriented at angles of 66.1 (7) and 60.0 (8)°, respectively. The two Br atoms are opposite the propen-1-one group. Weak inter­molecular C—H⋯O and C—H⋯π inter­actions are observed in the crystal structure.

Highlights

  • C29H22Br2O3, the dihedral angles between the mean planes of the benzene rings within each biphenyl group are 26.7 (8) and 30.9 (8)

  • The mean planes of the terminal and inner benzene rings of the biphenyl groups bonded through a propan-1-one group in the V-shaped molecule are oriented at angles of 66.1 (7) and 60.0 (8), respectively

  • The two Br atoms are opposite the propen-1-one group

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Summary

Crystal data

S. Yathirajanb a Department of Chemistry, Keene State College, 229 Main Street, Keene, NH 03435-2001, USA, bDepartment of Studies in Chemistry, University of Mysore, Manasagangotri, Mysore 570 006, India, and cDepartment of Studies in Chemistry, Mangalore University, Mangalagangotri, 574 199, India. R factor = 0.052; wR factor = 0.130; data-to-parameter ratio = 19.1. C29H22Br2O3, the dihedral angles between the mean planes of the benzene rings within each biphenyl group are 26.7 (8) and 30.9 (8). The mean planes of the terminal and inner benzene rings of the biphenyl groups bonded through a propan-1-one group in the V-shaped molecule are oriented at angles of 66.1 (7) and 60.0 (8) , respectively. The two Br atoms are opposite the propen-1-one group. Weak intermolecular C—H O and C—H interactions are observed in the crystal structure

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