Abstract

[57842-27-0] C7H5BF4S2 (MW 240.07) InChI = 1S/C7H5S2.BF4/c1-2-4-7-6(3-1)8-5-9-7;2-1(3,4)5/h1-5H;/q+1;-1 InChIKey = CUSWPJQKCZMDPY-UHFFFAOYSA-N (formyl2 and methyl cation3 equivalent; nucleoside hydroxyl protection group;4 1,1-dipole equivalent11) Physical Data: mp 150–150.5 °C (dec). Solubility: sol MeCN and DMF (slowly reacts); insol ether. Form Supplied in: light brown powder. Preparative Method: treatment of 2-(3-methylbutoxy)-1,3-benzodithiole2 with Tetrafluoroboric Acid in Acetic Anhydride at 0 °C. Purification: recrystallized from acetic acid or acetonitrile/ether. Handling, Storage, and Precautions: can be stored in the absence of moisture and light; no toxicity data is currently available; 1,3-benzodithiol-1-ium perchlorate [32283-21-9] is also known,2 but poses a risk of explosion.

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