Abstract
X-ray analysis reveals that both thiosemicarbazone groups of the title compound, [Fe(C 8 H 10 N 3 S) 2 ].H 2 O, are in the keto tautomeric form and that the configuration of the azomethine C=N double bond is E. The two cyclopentadienyl rings are parallel and nearly eclipsed. The crystal structure is stabilized by extensive intra- and intermolecular hydrogen bonding involving the water molecule and the thiosemicarbazone moieties.
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More From: Acta Crystallographica Section C Crystal Structure Communications
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