Abstract
The title salt, C11H15N2+·I−, crystallizes with two formula units in the asymmetric unit. The two crystallographically unique cations form alternating columns along the a axis, linked by protruding ethyl groups and interspersed with iodide counter-ions. Cations in a given column stack in centrosymmetrically related pairs with interionic C⋯C and C⋯N distances consistent with substantial π–π bonding. One of the iodide ions appears to form a weak hydrogen bond with the most acidic proton in one of the cations.
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