Abstract
A new class of vinylphosphonates, α-phosphonovinyl nonafluorobutanesulfonates ( i.e. nonaflates) is readily prepared from the corresponding acylphosphonates and nonafluorobutanesulfonyl fluoride in the presence of DBU. The obtained nonaflates are converted to the phosphono-containing enynes and dienes via Pd catalyzed coupling reactions.
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