α-Fe2O3 Nanoparticles/Iron-Containing Vermiculite Composites: Structural, Textural, Optical and Photocatalytic Properties

Abstract

Vermiculite two-dimensional mixed-layer interstratified structures are a very attractive material for catalysis and photocatalysis. The iron-containing vermiculite from the Palabora region (South Africa) and its samples, which calcined at 500 and 700 °C, were studied in comparison with the α-Fe2O3 nanoparticles/vermiculite composites for the first time as photocatalysts of methanol decomposition, which is an organic pollutant and an efficient source for hydrogen production. The aim of the work was to characterize their structural properties using X-ray fluorescence, X-ray diffraction, infrared spectroscopy, nitrogen physisorption, diffuse reflectance UV-Vis spectroscopy and photoluminescence spectroscopy to explain the photocatalytic effects. The photocatalytic test of the samples was performed in a batch photoreactor under UV radiation of an 8W Hg lamp. The photocatalytic activity of vermiculite–hydrobiotite–mica-like layers at different water hydration states in the interstratified structure and the substitution ratio of Fe(III)/Al in tetrahedra can initiate electrons and h+ holes on the surface that attack the methanol in redox processes. The activity of α-Fe2O3 nanoparticle photocatalysts stems from a larger crystallite size and surface area. The hydrogen production from the methanol–water mixture in the presence of vermiculites and α-Fe2O3 nanoparticles/vermiculite composites was very similar and higher than the yield produced by the commercial TiO2 photocatalyst Evonik P25 (H2 = 1052 µmol/gcat.). The highest yield of hydrogen was obtained in the presence of the Fe/V–700 composite (1303 µmol/gcat after 4 h of irradiation).