(μ-1,2-Dimethoxyethane-κ2O:O′)bis[(1,2-dimethoxyethane-κ2O,O′)tris(1,1,1,5,5,5-hexafluoro-4-oxopent-2-en-2-olato-κ2O,O′)cerium(III)

Abstract

A previous analysis [Fatila et al. (2012). Dalton Trans. 41, 1352-1362] of the title complex, [Ce(2)(C(5)HF(6)O(2))(6)(C(4)H(10)O(2))(3)], had identified it as Ce(hfac)(3)(dme)(1.5) according to the (1)H NMR integration [hfac = 1,1,1,5,5,5-hexafluoroacetylacetonate (1,1,1,5,5,5-hexafluoro-4-oxopent-2-en-2-olate) and dme = 1,2-dimethoxyethane]; however, it was not possible to determine the coordination environment unambiguously. The structural data presented here reveal that the complex is a binuclear species located on a crystallographic inversion center. Each Ce(III) ion is coordinated to three hfac ligands, one bidentate dme ligand and one monodentate (bridging) dme ligand, thus giving a coordination number of nine (CN = 9) to each Ce(III) ion. The atoms of the bridging dme ligand are unequally disordered over two sets of sites. In addition, in two of the -CF(3) groups, the F atoms are rotationally disordered over two sets of sites. This is the first crystal structure of a binuclear lanthanide β-diketonate with a bridging dme ligand.