Abstract
The chemistry of transition metal complexes, especially that of metal clusters, may contribute to the better understanding of surface reactions at molecular level. There are potential analogies between metal clusters and metal surface with respects to i) nature of metal-metal bonding network, ii) metal-organic species interaction, and iii) mobility of organic species on metals, as pointed out by E.L. Muetterties. Metal clusters and metal surface have also similarity with respect to metal rearrangement as well as to hydrogen migration on the inside of the metal network. New notation for the chemisoption process, which has been proposed recently, is described briefly.
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