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Влияние микрорельефа и степени выгорания поверхности на водно-физические свойства торфяной залежи и характеристики химического состава вод постпирогенных болот Западной Сибири

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This study examines how microrelief and surface burning influence hydrological and chemical properties of peat bogs in Western Siberia's forest-tundra and taiga zones. Post-fire changes include decreased oxygen and Eh levels, increased pH, EC, CO2, and temperature, with variations depending on burn severity and initial surface conditions. Burnt bogs show decreased hydraulic conductivity in taiga zones due to structural disruption, while in forest-tundra areas, conductivity increases owing to thermal regime changes. Water table levels tend to rise after fires, but the correlation with surface microtopography weakens as burn depth increases, disrupting water storage capacity.

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The paper analyzes changes in the hydrological characteristics and water chemistry of mires in the forest-tundra and taiga zones of Western Siberia under the influence of the pyrogenic factor at the microlevel. In the taiga zone, research was carried out in drained sites of the Bakchar Bog (spurs of the Great Vasyugan Mire) and Ust-Bakchar bog, in the forest-tundra on a pristine palsa near Pangody village. All studied mires burned out in 2014−2016. The studies were carried out on 12 model key plots with an area 25 m2, where the water chemistry, hydraulic conductivity and water table levels were determined in 9 wells linked to the surface microtopography. The surface surface microtopography was surveyed using a SOKKIL CX-105 tacheometer with a step of 50 cm. The hydraulic conductivity was determined in the 0-50 cm and 50-100 cm layers by pumping using a Solinst 428 sampler. Analysis of the background sites showed initial differences in water chemistry characteristics, the bogs of the taiga zone were drained, as a result, higher O2 content, pH values, Eh, EC, as well as temperature were noted in the samples due to a more southern location. The palsa near Pangody village was not drained, therefore, lower pH and EC were noted in the waters, but the CO2 content was higher due to the active processes of decomposition of plant residues under leaching conditions. Studies have shown that after fires, due to the formation of a hydrophobic layer on the surface, there is a decrease in the O2 content and Eh values in waters, and vice versa, there is an increase in pH, EC, CO2 concentration and temperature. Under background unburn conditions, the studied characteristics smoothly decrease from hummock to hollow, and under pyrogenic conditions, variations in pH, EC, T, Eh, CO2, O2 in waters strongly depend on the degree of burnout and the initial transformation of the surface under the influence of drainage. Under the influence of the pyrogenic factor, water table levels increase; with increasing thickness of the burnt layer, the correlation between the height of the surface and the position of water table levels decreases, since the water storage capacity of the upper layer of the peat deposit is disrupted. Hydraulic conductivity in peat deposits of burnt bogs in the taiga zone decrease due to disruption of the porous structure of the upper peat layer, and in the forest-tundra it increase as a result of transformation of the thermal regime. Higher hydraulic conductivity are observed in hollows and at the middle surface level, and, conversely, decrease in hummocks.

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Preferential flow in geosynthetic clay liners exhumed from final covers with composite barriers
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Geosynthetic clay liners (GCLs) were exhumed from final covers with composite barriers (geomembrane over GCL) at two municipal solid waste landfills in the USA. Preferential flow and high hydraulic conductivity (>2 × 10−9 m/s) was observed in eight of the 18 GCL samples collected from both sites. At one site, manganese oxide precipitate was concomitant with bundles of needle-punched fibers that conducted preferential flow. Nearly complete replacement of Na by Ca on the bentonite surface occurred in all GCL samples. GCLs with and without preferential flow could not be differentiated by physical and chemical properties commonly used to differentiate GCLs with high and low hydraulic conductivities (exhumed water content, swell index, mole fraction monovalent cations, soluble cation concentrations). The relative abundance of soluble cations in the pore water of GCLs exhibiting preferential flow was comparable to the relative abundance in the subgrade pore water, whereas the pore water in GCLs with distributed flow was more sodic than the pore water in the subgrade. Hydration experiments indicated that bentonite in GCLs initially hydrates in a zone surrounding bundles of needle-punching fibers. Cation exchange during this hydration process may create zones of higher hydraulic conductivity surrounding the fiber bundle, permitting preferential flow.

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